Between red and yellow: evidence of intermediates in a vapochromic Pt(Ⅱ) saltt

Stephen D. Taylor; Amie E. Norton; Robert T. Hart Jr; Mahmood K. Abdolmaleki; Jeanette A. Krause; William B. Connick

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Between red and yellow: evidence of intermediates in a vapochromic Pt(Ⅱ) saltt

机译：在红色和黄色之间：气相致变色Pt（Ⅱ）盐溶液中的中间体的证据

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[Pt(tpy)Cl]ClO_4 H_2O (1H_2O) changes from red to yellow upon dehydration due to increased Pt...Pt distances. Spectroscopic, diffraction, gravimetric and calorimetric data demonstrate the presence of intermediates during hydration and dehydration which signifies surprising mechanistic complexity in the vapochromic response.

机译：[Pt（tpy）Cl] ClO_4 H_2O（1H_2O）脱水后由于Pt ... Pt距离增加而从红色变为黄色。光谱，衍射，重量和量热数据表明，在水合和脱水过程中存在中间体，这表明蒸气致变色反应中令人惊讶的机械复杂性。

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《Chemical Communications》 |2013年第80期|9161-9163|共3页
作者
Stephen D. Taylor; Amie E. Norton; Robert T. Hart Jr; Mahmood K. Abdolmaleki; Jeanette A. Krause; William B. Connick;
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Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH 45221-0172, USA,The Shepherd Chemical Company, 4900 Beech St., Norwood, OH 45212, USA;

Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH45221-0172, USA;

The Shepherd Chemical Company, 4900 Beech St., Norwood, OH 45212, USA;

Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH45221-0172, USA;

Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH45221-0172, USA;

Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH45221-0172, USA;

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入库时间 2022-08-17 13:18:43

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Between red and yellow: evidence of intermediates in a vapochromic Pt(Ⅱ) saltt

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