Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic estersf

Yuan-Liang Yang; Zhen Zhang; Xiao-Nan Zhang; De Wang; Yin Wei; Min Shi

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Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic estersf

机译：Lewis碱催化的环丙烯酮反应：单取代或多取代的烯丙基酯的新颖合成f

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摘要

The reactions of cyclopropenones with nucleophiles (H_2O or methanol) could be catalyzed by nitrogen-containing Lewis bases or phosphorus-containing Lewis bases, affording the corresponding mono- or multi-substituted allenic esters in moderate to excellent yields.

机译：环丙烯酮与亲核试剂（H_2O或甲醇）的反应可以通过含氮的路易斯碱或含磷的路易斯碱催化，以中等至极好的收率得到相应的单或多取代的烯丙酸酯。

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《Chemical Communications》 |2014年第1期|115-117|共3页
作者
Yuan-Liang Yang; Zhen Zhang; Xiao-Nan Zhang; De Wang; Yin Wei; Min Shi;
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作者单位

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 tingling Road, Shanghai 200032, P. R. China;

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机译：Tropone和Cyclopropenone的二甲基缩酮的合成与表征

Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic estersf

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