Acidity and Catalytic Behaviors of Ordered Mesoporous Aluminosilicate Materials Containing Zeolite Building Units

Ayyamperumal Sakthivel; Wen-Hua Chen; Shou-Heng Liu; Shing-Jong Huang; An-Ya Lo; Ying-Hou Hsu; Shawn D. Lin; Shang-Bin Liu

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Acidity and Catalytic Behaviors of Ordered Mesoporous Aluminosilicate Materials Containing Zeolite Building Units

机译：含沸石结构单元的有序介孔铝硅酸盐材料的酸度和催化行为

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The structural and acidic properties of two new highly stable meso-/microporous composite materials (MMS-H and RMM-1) developed recently were characterized by various analytical and spectroscopic techniques. Comparing to their structural analogue, Al-MCM-48, these novel aluminosilicates materials comprising zeolite secondary building units were found to have superior catalytic activities, as illustrated by ethylbenzene alkylation reaction.

机译：最近开发的两种新型高度稳定的介孔/微孔复合材料（MMS-H和RMM-1）的结构和酸性性质通过各种分析和光谱技术进行了表征。与它们的结构类似物Al-MCM-48相比，发现这些包含沸石二级结构单元的新型铝硅酸盐材料具有优异的催化活性，如乙苯烷基化反应所示。

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来源
《Catalysis Letters》 |2006年第4期|173-178|共6页
作者
Ayyamperumal Sakthivel; Wen-Hua Chen; Shou-Heng Liu; Shing-Jong Huang; An-Ya Lo; Ying-Hou Hsu; Shawn D. Lin; Shang-Bin Liu;
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作者单位

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

Department of Chemical Engineering Yuan Ze University Chungli 320 Taiwan R.O.C;

Department of Chemical Engineering Yuan Ze University Chungli 320 Taiwan R.O.C;

Institute of Atomic and Molecular Sciences Academia Sinica P.O. Box 23-166 Taipei 106 Taiwan R.O.C;

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mesoporous aluninosilicate material; zeolite building units; characterization; acidity; stability; ethylbenzene alkylation;

机译：介孔硅铝酸盐材料;沸石结构单元;表征;酸度;稳定性;乙苯烷基化;

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专利

1. Acidity and catalytic behaviors of ordered mesoporous aluminosilicate materials containing zeolite building units [J] . Wen-Hua Chen, Shou-Heng Liu, Shing-Jong Huang, Catalysis Letters . 2006,第3a4期

机译：含沸石结构单元的有序介孔铝硅酸盐材料的酸度和催化行为
2. Acidic and catalytic properties of hierarchical zeolites and hybrid ordered mesoporous materials assembled from MFI protozeolitic units [J] . Serrano D.P., García R.A., Vicente G., Journal of Catalysis . 2011,第2期

机译：由MFI原生沸石单元组装而成的分级沸石和杂化有序介孔材料的酸性和催化性能
3. Catalytic Fast Pyrolysis of Lignin over High-Surface-Area Mesoporous Aluminosilicates: Effect of Porosity and Acidity [J] . Custodis Victoria B. F., Karakoulia Stamatia A., Triantafyllidis Kostas S., ChemSusChem . 2016,第10期

机译：木质素催化快速热解，高表面积介孔硅酸盐：孔隙率和酸度的影响
4. Enhanced acidity and hydro thermal stability of mesoporous aluminosilicate with secondary building units characteristic of zeolite Beta [C] . Wanping Guo, Lingdong Kong, Chang-Sik Ha, International mesostructured materials symposium . 2003

机译：具有沸石β的二级建筑单位的中孔硅铝酸酯的酸度和水力热稳定性
5. Synthesis, characterization, and catalytic application of strongly acidic mesoporous aluminosilicate materials [D] . Wang, Hui 2007

机译：强酸性介孔硅铝酸盐材料的合成，表征和催化应用
6. Isolation and immobilization of alkaline protease on mesoporous silica and mesoporous ZSM-5 zeolite materials for improved catalytic properties [O] . Arpana Kumari, Balwinder Kaur, Rajendra Srivastava, 2015

机译：碱性蛋白酶在介孔二氧化硅和介孔ZSM-5沸石材料上的分离和固定以改善催化性能
7. Isolation and immobilization of alkaline protease on mesoporous silica and mesoporous ZSM-5 zeolite materials for improved catalytic properties [O] . Kumari Arpana, Kaur Balwinder, Srivastava Rajendra, 2015

机译：碱性蛋白酶在中孔二氧化硅和中孔ZSM-5沸石材料上的分离和固定，以改善催化性能

Acidity and Catalytic Behaviors of Ordered Mesoporous Aluminosilicate Materials Containing Zeolite Building Units

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