GILDINGS AND FALSE GILDINGS OF THE BAROQUE AGE: CHARACTERIZATION AND CONSERVATION PROBLEMS

摘要

This work investigates the decayed decoration of the ‘Vergine del Carmelo’ chapel, with a particular interest in the residual gildings. Samples of the finishing layers were examined by VIS-UV optical microscopy and scanning electron microscopy coupled with EDX spectrometry, in order to evaluate the unusual degradation phenomena. Mineralogical composition of the stucco substrate was characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The results showed the unexpected presence of a thick layer of brass flakes, applied without any binder, used as a substitute for the damaged original gold leaf, and highlighting a very uncommon selective corrosion process of the brass.