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Design and fabrication of NiS/LaFeO_3 heterostructures for high efficient photodegradation of organic dyes

机译:NiS / LaFeO_3异质结构的设计和制备,用于有机染料的高效光降解

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摘要

A new heterostructures of NiS/LaFeO3 (NiS/LFO), which has the morphology of LFO nanoparticles fixed NiS nanosheetes, has been well designed and successfully fabricated by a facile two-step hydrothermal method. To be used in photodegradation of anion MO dye, it can possess the removal efficiency of 90.9% and reaction rate constant of 0.0169 min(-1), being approximately 12 times higher than that of pure LFO (0.0014 min(-1)). Detailed investigations show that such excellent photocatalytic performance of NiS/LFO should be attributed to nanosheet structure of NiS to unimpededly transport the photogenerated electrons, and the matched energy band of NiS and LFO for better interfacial electrons separation and transfer. The present study might induce a new means to design and fabricate new LFO-based heterostructured photocatalysts for high efficient photodegradation.
机译:具有良好结构的LSO纳米颗粒固定了NiS纳米片的NiS / LaFeO3(NiS / LFO)新型异质结构已经通过良好的两步水热方法进行了精心设计和成功制备。可用于阴离子MO染料的光降解,具有90.9%的去除效率和0.0169 min(-1)的反应速率常数,约为纯LFO(0.0014 min(-1))的12倍。详细的研究表明,NiS / LFO的这种出色的光催化性能应归因于NiS的纳米片结构来无阻碍地传输光生电子,以及NiS和LFO的能带匹配以实现更好的界面电子分离和转移。本研究可能会导致一种新的手段来设计和制造基于LFO的新型异质结构光催化剂,以实现高效的光降解。

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