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Three-dimensional porous MXene/NiCo-LDH composite for high performance non-enzymatic glucose sensor

机译:用于高性能非酶葡萄糖传感器的三维多孔MXene / NiCo-LDH复合材料

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摘要

In this paper, Nickel-Cobalt layered double hydroxide (NiCo-LDH) nanosheets were first in situ synthesized on MXene (Ti3C2) via a simple hydrothermal method, then glucose sensing performance based on three-dimensional porous MXene/NiCo-LDH nanocomposite was explored. At a working potential of 0.45 V (vs. SCE), the glucose sensor exhibits a wide linearity range (0.002 mM-4.096 mM), a low limit of detection (0.53 mu M) and a rapid response ( < 3 s). Moreover, good selectivity, reproducibility and stability were also obtained. And the excellent performance can attribute to large area of contact of materials surface with glucose, fast electron transfer rate and easy diffusion of electrolyte provided by the novel 3D porous NiCo-LDH nanosheets on the conducive MXene substrate. Therefore, MXene/NiCo-LDH composites will be a candidate for electrochemical detection of glucose.
机译:本文首先通过简单的水热法在MXene(Ti3C2)上原位合成了镍钴层状双氢氧化物(NiCo-LDH)纳米片,然后研究了基于三维多孔MXene / NiCo-LDH纳米复合材料的葡萄糖传感性能。 。在0.45 V(vs. SCE)的工作电位下,葡萄糖传感器显示出宽线性范围(0.002 mM-4.096 mM),低检测限(0.53μM)和快速响应(<3 s)。此外,还获得了良好的选择性,重现性和稳定性。优异的性能归因于新型3D多孔NiCo-LDH纳米片材在有益MXene基底上提供的材料表面与葡萄糖接触的面积大,电子转移速度快以及电解质易于扩散等优点。因此,MXene / NiCo-LDH复合材料将成为电化学检测葡萄糖的候选材料。

著录项

  • 来源
    《Applied Surface Science》 |2019年第30期|143554.1-143554.9|共9页
  • 作者单位

    Chongqing Univ Coll Phys State Key Lab Mech Transmiss Chongqing Key Lab Soft Condensed Matter Phys & Sm Chongqing 400044 Peoples R China;

    Chongqing Univ Posts & Telecommun Sch Optoelect Engn Chongqing Key Lab Photoelect Informat Sensing & T Chongqing 400065 Peoples R China;

    Chongqing Normal Univ Key Lab Optoelect Funct Mat Coll Phys & Elect Engn Chongqing 401331 Peoples R China;

    Chongqing Univ Natl Engn Res Ctr Magnesium Alloys Coll Mat Sci & Engn Chongqing 400044 Peoples R China;

    Chongqing Univ Coll Chem & Chem Engn Chongqing 401331 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    MXene; Layer double hydroxide; Glucose sensor; Chronoamperometry;

    机译:MXene;层状双氢氧化物;葡萄糖传感器计时电流法;

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