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Construction of superhydrophobic copper film on stainless steel mesh by a simple liquid phase chemical reduction for efficient oil/water separation

机译:通过简单的液相化学还原在不锈钢网上构建超疏水性铜膜,以实现有效的油/水分离

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摘要

Herein, we present a simple, easily operated, and inexpensive approach to fabricate superhydrophobic and superoleophilic stainless steel mesh via in-situ growth of copper (Cu) nanoparticles and the hydrophobic modification. The obtained meshes exhibit favorable resistance to mechanical abrasion, corrosive aqueous solutions, and hot water (90 degrees C). More importantly, the fabricated meshes can be used to separate a series of oil/water mixtures under harsh (hot or corrosive water) conditions with a separation efficiency of over 98%. Besides, the mesh can be designed into an oil collector via loading unmodified polyurethane (PU) sponge in the folded mesh box, which can quickly and selectively remove oil pollutants floating on water surface. Therefore, it can be expected that the as-prepared mesh with good superhydrophobicity and easy operated fabrication process may provide a candidate not only for gravity driven oil/water separation but also for designing many other oil collector.
机译:本文中,我们提出了一种简单,易于操作且便宜的方法,通过铜(Cu)纳米粒子的原位生长和疏水改性来制造超疏水和超亲油性不锈钢网。所获得的筛网表现出良好的抗机械磨损性,腐蚀性水溶液和热水(90摄氏度)。更重要的是,在苛刻的(热水或腐蚀性水)条件下,可使用制成的筛网分离一系列油/水混合物,分离效率超过98%。此外,可通过将未改性的聚氨酯(PU)海绵装入折叠的网箱中,将网设计成集油器,从而可以快速,选择性地去除浮在水面上的油污。因此,可以预期的是,具有良好的超疏水性和易于操作的制造过程的所制备的筛网不仅可以为重力驱动的油/水分离提供候选,而且可以为设计许多其他集油器提供候选。

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