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Additive manufactured new hybrid high entropy alloys derived from the AlCoFeNiSmTiVZr system

机译:由AlCoFeNiSmTiVZr系统衍生的增材制造的新型混合高熵合金

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Several million high entropy alloys (HEAs) are possible just using the combination of similar to 37 main elements. However, the HEA count in the literature hardly exceeds 450. Hence, a great need and opportunity exist with an objective of producing robust and durable alloys. Though various equiatomic HEAs have been explored, efforts in the direction of the utility of lanthanides/rare earth elements and refractory elements with the combination of 3d transition metals and aluminum have not been well-established. In order to further explore such alloys, several new hybrid HEAs namely AlCoFeNiV0.9Sm0.1, AlCoFeNiSm0.1TiV0.9, AlCoFeNiSm0.05TiV0.95Zr, and a bulk metallic glass AlCoFeNiTiVZr were manufactured using the selective laser melting technique. Most of these alloys are single phase FCC (face-centered cubic) structures as revealed by X-Ray diffraction analysis and other characterization techniques. These alloys exhibit excellent mechanical and corrosion resistant properties as revealed by first principles based calculations and experimental examinations.
机译:仅仅使用类似于37种主要元素的组合,就有可能实现数百万种高熵合金(HEA)。但是,文献中的HEA数几乎不超过450。因此,以生产坚固耐用的合金为目标,存在着巨大的需求和机会。尽管已经探索了各种等原子的HEA,但是在结合3d过渡金属和铝的镧系元素/稀土元素和难熔元素的应用方向上的努力尚未建立。为了进一步探索这种合金,使用选择性激光熔化技术制造了几种新型混合HEA,即AlCoFeNiV0.9Sm0.1,AlCoFeNiSm0.1TiV0.9,AlCoFeNiSm0.05TiV0.95Zr和块状金属玻璃AlCoFeNiTiVZr。 X射线衍射分析和其他表征技术表明,这些合金大多数是单相FCC(面心立方)结构。这些合金表现出优异的机械和耐腐蚀性能,这是基于基于第一原理的计算和实验检验所揭示的。

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