Flexible Fe_3O_4 nanoparticles/N-doped carbon nanofibers hybrid film as binder-free anode materials for lithium-ion batteries

摘要

The energy and power density of lithium-ion batteries (LIBs) can be effectively improved by designing flexible free-standing electrodes. Here, a flexible film composed of Fe3O4 nanoparticles (NPs) embedded in N-doped carbon nanofibers (Fe3O4/NCNFs) was prepared through electrospinning and subsequent annealing process. The Fe3O4/NCNFs film can be directly used as anode materials for LIBs without conducive additive, current collector, and binder. Electrochemical measurement results indicate that the Fe3O4/NCNFs electrode exhibits excellent cycling stability and retains the capacity of 522 mAh g(-1) after 200 cycles at 0.1 A g(-1). Furthermore, the Fe3O4/NCNFs electrode also shows good rate performance and still obtains a specific capacity of 407 mAh g(-1) even at 5 A g(-1). The superior electrochemical performance should be attributed to the flexible self-standing characteristic of the electrode and the synergistic effects between 3D conducive NCNFs and Fe3O4 NPs.