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Deposition of superhydrophobic nanostructured Teflon-like coating using expanding plasma arc

机译:使用扩展的等离子弧沉积超疏水纳米结构的特氟龙状涂层

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摘要

A novel approach was used to grow nanostructured Teflon-like superhydrophobic coatings on stainless steel (SS). In this method Teflon tailings were pyrolyzed to generate fluorocarbon precursor molecules, and an expanding plasma arc (EPA) was used to polymerize these precursors to deposit Teflon-like coating. The coating shows super hydrophobic behavior with water contact angle (WCA) of 165°. The coating was observed to be uniform. It consists of nanostructured (~80-200 nm) features, which were confirmed by scanning electron microscopy. The chemical bond state of the film was determined by XPS and FTIR, which indicate the dominance of -CF_2 groups in the deposited coating. The combination of nanofeature induced surface roughness and the low surface energy imparted by Teflon-like coating is responsible for the observed superhydrophobic nature.
机译:一种新颖的方法被用来在不锈钢(SS)上生长纳米结构的特氟龙状超疏水涂层。在这种方法中,将聚四氟乙烯尾矿热解以生成碳氟化合物前体分子,并使用扩展的等离子弧(EPA)聚合这些前体以沉积类似聚四氟乙烯的涂层。该涂层显示出超疏水性能,水接触角(WCA)为165°。观察到涂层是均匀的。它具有纳米结构(〜80-200 nm)的特征,已通过扫描电子显微镜证实。膜的化学键状态由XPS和FTIR确定,表明沉积涂层中-CF_2基团占优势。纳米特征引起的表面粗糙度与类聚四氟乙烯涂层赋予的低表面能的结合是观察到的超疏水性的​​原因。

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