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Chemical Synthesis Of Nano-porous Ruthenium Oxide (ruo_2) Zthin Films For Supercapacitor Application

机译:用于超级电容器的纳米多孔氧化钌(ruo_2)Zthin膜的化学合成

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摘要

Ruthenium oxide (RuO_2) thin films have been prepared using single step chemical method containing Ru(III) Cl_3 solution in an aqueous medium at low temperature. The structural, morphological and optical properties have been investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and optical absorption technique. The XRD study revealed the formation of amorphous RuO_2 thin film. The surface examination by SEM showed formation of nano-porous material on the substrate. The TEM study revealed the formation of nanostructured material. The optical absorption studies showed the presence of direct band transition with band gap equal to 2.2 eV. The RuO_2 has proved its applicability in supercapacitor showing 50 F/g specific capacitance in 0.5 M H_2SO_4 at 20 mV/s scan rate.
机译:氧化钌(RuO_2)薄膜是采用单步化学方法制备的,该方法在低温下于水性介质中包含Ru(III)Cl_3溶液。使用X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM)和光吸收技术研究了结构,形态和光学性质。 XRD研究表明形成了非晶态的RuO_2薄膜。通过SEM的表面检查显示在基材上形成纳米多孔材料。 TEM研究揭示了纳米结构材料的形成。光吸收研究表明存在带隙等于2.2 eV的直接带跃迁。 RuO_2已证明其在超级电容器中的适用性,在20 mV / s的扫描速率下,在0.5 M H_2SO_4中具有50 F / g的比电容。

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