Studies on adsorptions of metallic ions in water by zirconium glyphosate (ZrGP): Behaviors and mechanisms

摘要

A new adsorbent named zirconium glyphosate [Zr(O_3PCH_2NHCH_2COOH)_2-0.5H_2O, denoted as ZrGP] and its selective adsorptions to Pb~(2+), Cd~(2+), Mg~(2+) and Ca~(2+) ions in water were reported in this paper. Compared to other zirconium adsorbents, such as zirconium phosphate [Zr(HPO_4)_2], ZrGP exhibited highly selective adsorption to Pb~(2+) in solution which contained Pb~(2+), Cd~(2+), Mg~(2+) and Ca~(2+) ions. The loaded ZrGP with metallic ions can be efficaciously regenerated by aqueous solution of HC1 (1.0 M) without any noticeable capacity loss, and almost all of it can be reused and recycled. The memory effect on structural regeneration of ZrGP was also found when Mg~(2+) and Ca~(2+) were adsorbed. To be specific, the structure of ZrGP was destroyed due to adsorbing these two ions, but it could be regenerated after the loaded materials were dipped in HCl solution (1.0M) for several minutes to remove metallic ions.