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Photodegradation of methyl orange with PANI-modified BiOCl photocatalyst under visible light irradiation

机译:PANI修饰的BiOCl光催化剂在可见光下光降解甲基橙

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摘要

Photocatalyst BiOCl modified by polyaniline (PANI/BiOCl) was synthesized via a facile chemisorptions method. X-ray diffraction (XRD), Scanning electron microscopy (SEM) and UV-vis diffuse reflectance spectroscopy (DRS) were employed to study the phase structure, morphology and optical properties of the samples. The results showed that the PANI increased absorption intensity and absorption bands of the pure BiOCl. Photodegradation of methyl orange (MO) on the samples were investigated under visible light irradiation and 7 wt.% PANI/BiOCl composite showed the highest photocatalytic activity. The enhanced photocatalytic performance could be attributed to PANI/BiOCl composites and the synergistic effect between PANI and BiOCl. According to experimental results, the possible photocatalytic mechanism of the PANI/BiOCl photocatalysts was proposed.
机译:聚苯胺(PANI / BiOCl)修饰的光催化剂BiOCl是通过一种简便的化学吸附方法合成的。利用X射线衍射(XRD),扫描电子显微镜(SEM)和紫外可见漫反射光谱(DRS)研究了样品的相结构,形貌和光学性质。结果表明,PANI增加了纯BiOCl的吸收强度和吸收带。在可见光照射下研究了样品上甲基橙(MO)的光降解,并且7 wt%的PANI / BiOCl复合材料显示出最高的光催化活性。增强的光催化性能可以归因于PANI / BiOCl复合材料以及PANI和BiOCl之间的协同作用。根据实验结果,提出了PANI / BiOCl光催化剂可能的光催化机理。

著录项

  • 来源
    《Applied Surface Science》 |2013年第15期|577-583|共7页
  • 作者单位

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China,Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Gansu Polymer Materials, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

    College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    PANI/BiOCl; Photocatalysis; Synergistic effect; Photodegradation;

    机译:PANI / BiOCl;光催化;协同效应;光降解;

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