Preparation of silver-cuprous oxide/stearic acid composite coating with superhydrophobicity on copper substrate and evaluation of its friction-reducing and anticorrosion abilities

摘要

A simple two-step solution immersion process was combined with surface-modification by stearic acid to prepare superhydrophobic coatings on copper substrates so as to reduce friction coefficient, increase wear resistance and improve the anticorrosion ability of copper. Briefly, cuprous oxide (Cu_2O) crystal coating with uniform and compact tetrahedron structure was firstly created by immersing copper substrate in 2 mol L~(-1) NaOH solution. As-obtained Cu_2O coating was then immersed in 0.33 mmol L~(-1) AgNO_3 solution to incorporate silver nanoparticles, followed by modification with stearic acid (denoted as SA) coating to achieve hydrophobicity. The surface morphology and chemical composition of silver-cuprous oxide/stearic acid (denoted as Ag-Cu_2O/SA) composite coating wre investigated using a scanning electron microscope and an X-ray photoelectron spectroscope (XPS); and its phase structure was examined with an X-ray diffractometer (XRD). Moreover, the contact angle of water on as-prepared Ag-Cu_2O/SA composite coating was measured, and its friction-reducing and anticorrosion abilities were evaluated. It was found that as-prepared Ag-Cu_2O/SA composite coating has a water contact angle of as high as 152.4° and can provide effective friction-reducing, wear protection and anticorrosion protection for copper substrate, showing great potential for surface-modification of copper.