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The effect of incorporated self-lubricated BN(h) particles on the tribological properties of Ni-P/BN(h) composite coatings

机译:掺入自润滑BN(h)颗粒对Ni-P / BN(h)复合涂层的摩擦学性能的影响

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摘要

Ni-P/BN(h) composite coatings are prepared by means of the conventional electroless plating from the bath containing up to 10.0 g/l of hexagonal boron nitride particles with size 0.5 mu m. The Ni-P coating is also prepared as a comparison. Cationic surfactant cetyltrimethylammonium bromide (CTAB) is used to stabilize the electrolyte, and the optimum CTAB concentration resulting in a nonagglomerated dispersion of particles is obtained using a dispersion stability analyzer. Morphology of the coatings and the effect of incorporated particles on coating structure and composition are investigated via scanning electron microscopy, field emission electron probe micro-analyzer and X-ray diffraction analysis. Hardness, roughness, friction coefficient and wear resistance of the coatings are also evaluated using Vickers microhardness tester, atomic force microscopy and ball-on disk machine. The presence of CTAB in the depositing bath has a positive effect on the surface roughness and performance of Ni-P/BN(h) composite coatings. The friction and wear tests results show that incorporation of 14.5 vol% BN(h) particles into the Ni-P coating lowers the coating friction coefficient by about 75% and the wear resistance of the Ni-P composites is approximately 10 times higher than Ni-P coating. (C) 2015 Elsevier B.V. All rights reserved.
机译:Ni-P / BN(h)复合涂层是通过传统的化学镀方法从镀液中制备的,镀液中含有高达10.0 g / l的尺寸为0.5μm的六方氮化硼颗粒。作为比较也准备了Ni-P涂层。使用阳离子表面活性剂溴化十六烷基三甲基铵(CTAB)来稳定电解质,并使用分散稳定性分析仪获得导致颗粒无团聚分散的最佳CTAB浓度。通过扫描电子显微镜,场发射电子探针显微分析仪和X射线衍射分析,研究了涂层的形貌以及掺入的颗粒对涂层结构和组成的影响。涂层的硬度,粗糙度,摩擦系数和耐磨性也使用维氏显微硬度计,原子力显微镜和滚珠圆盘机进行评估。沉积浴中CTAB的存在对Ni-P / BN(h)复合涂层的表面粗糙度和性能具有积极影响。摩擦磨损测试结果表明,将14.5%(体积)的BN(h)颗粒掺入Ni-P涂层可使涂层的摩擦系数降低约75%,Ni-P复合材料的耐磨性比Ni高约10倍。 -P涂层。 (C)2015 Elsevier B.V.保留所有权利。

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