Optical properties of graphene oxide and reduced graphene oxide determined by spectroscopic ellipsometry

摘要

Graphical abstract Display Omitted Highlights • Anisotropic optical constants of graphene oxide from spectroscopic ellipsometry. • Coverage levels of graphene sheets with oxygen containing functional groups. • In situ study of reduction of graphene oxide by exposure to broad-band white light. • Reduced graphene oxide optical constants from multiple time step analysis. Abstract We report the optical constants of graphene oxide and reduced graphene oxide determined by spectroscopic ellipsometry. The dynamic changes in optical properties and thickness of a drop-cast graphene oxide layer during reduction by long-term exposure to focused broad-band white light are monitored in situ. The anisotropic optical constants of the graphene oxide layer and the isotropically averaged optical constants of the reduced layer are precisely determined from a multiple-location analysis of spatially resolved data across the exposed location and a multiple-time-step analysis of the dynamic data, respectively. Observed inter-band transitions in the graphene oxide layer are discussed in relation to theoretical predictions for different coverage levels of the graphene oxide sheets with oxygen containing functional groups. The derived optical constants of the reduced graphene oxide layer are compared to reported values of graphene and thermally reduced graphene oxide.