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Evolution of controllable urchin-like SrCO3 with enhanced electrochemical performance via an alternative processing

机译:通过可替代的工艺发展出可控的类似顽童的SrCO3,具有增强的电化学性能

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摘要

Strontium carbonate (SrCO3) owning an urchin-like morphology with a hierarchical nanostructure was synthesized by the reactants of strontium nitrate and urea via a facilitative, green initiative hydrothermal route. Samples characterization results of the structure showed that the surface of urchin-like SrCO3 was evenly distributed with nanorods with a diameter of about 50 nm and lengths of 1-2 mu m. It was also found that the hydrothermal reaction time and reactants of trace concentrations changes will have an impact on the size and morphology. For these reasons we presented the crystal growth mechanism of "nuclear aggregates-nanorods embellishment-urchin-like" during the process of fabricating urchin-like SrCO3 crystal. Specific capacitance was enhanced more than 6 times, which dug out the optimal urchin-like SrCO3 influenced by a growth of surface nanorods. (C) 2017 Elsevier B.V. All rights reserved.
机译:硝酸锶与尿素的反应物通过便利的绿色主动水热途径合成了具有分级纳米结构的海胆状形态的碳酸锶(SrCO3)。结构的样品表征结果表明,海胆状SrCO3的表面均匀分布着直径约50 nm,长度1-2μm的纳米棒。还发现水热反应时间和反应物的痕量浓度变化将对尺寸和形态产生影响。由于这些原因,我们提出了在制造类似海胆的SrCO3晶体的过程中“核聚集体-纳米点缀-海胆状”的晶体生长机理。比电容提高了6倍以上,从而挖掘出了受表面纳米棒生长影响的最佳顽童状SrCO3。 (C)2017 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2017年第31期|197-204|共8页
  • 作者单位

    Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Funct Mat Lab, Xian 710055, Peoples R China;

    Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Funct Mat Lab, Xian 710055, Peoples R China;

    Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Funct Mat Lab, Xian 710055, Peoples R China;

    Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Funct Mat Lab, Xian 710055, Peoples R China;

    Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Funct Mat Lab, Xian 710055, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    SrCO3; Urchin-like structure; Nanorods; Crystal growth; Electrochemical capacitance;

    机译:SrCO3;Urchin样结构;纳米棒;晶体生长;电化学电容;

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