The solid reaction of lithium hydride and lithium hydroxide in lithium hydride pellet under normal condition and the application of CO_2 for long-time storage

摘要

The solid reaction of lithium hydride and lithium hydroxide in lithium hydride pellet is first directly observed at normal ambient condition after 4 years storage. Layer-by-layer XPS results show that LiOH hydrolysis layer quickly forms on the LiH surface, LiOH reacts with bulk LiH to form Li2O and H-2. Due to the great H-2 outgassing after long time conservation, bubbling problem actually exists during the practical long-time preserving period. Using CO2 as pre-treatment gas during the LiH sample preparation process is a feasible way to prevent LiH sample from bubbling after long storage period. Moreover, Li2CO3 shows possible delay effect on the solid reaction of LiOH with LiH in this work, thus preserving LiH sample in CO2 containing atmosphere might also be an prospective way to protect the sample from further corrosion. (C) 2018 Elsevier B.V. All rights reserved.