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A facile synthesis of interconnected CuO nanosheets: a promising electrode material for supercapacitor application

机译:相互连接的CuO纳米晶片的容易合成:超级电容器应用的有希望的电极材料

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摘要

In this endeavor, the interconnected CuO nanosheets were prepared using the cetyl trimethyl ammonium bromide-assisted sonochemical synthetic route followed by a proper calcination process. The X-ray diffraction analysis and Fourier transform infrared spectroscopic analysis were utilized to examine the phase and internal bonding properties of the freshly prepared CuO materials. The morphological properties were analyzed through a high-resolution scanning electron microscope which confirms the formation of interconnected CuO nanosheets. Due to the unique nanosheet structure, the CuO nanosheets provide the maximum specific capacitance of 667 Fg~(-1) at a scan rate of 5 mVs~(-1). The galvanostatic charge/discharge measurements render the specific capacitance of 638 Fg~(-1) at a current density of 1 Ag~(-1) and provide 31.8 W h Kg~(-1) and 94 22 W Kg~(-1) energy and power densities, respectively. The cyclic stability studies exhibit remarkable stability such as 81% of initial capacitance withstand after 3000 cyclic voltammetric cycles at a scan rate of 100 mVs~(-1). All these outcomes demonstrated that the interconnected CuO nanosheets are auspicious for probable application in supercapacitors and other fields of application.
机译:在这种努力中,使用甲丁基三甲基溴化铵辅助的SOPOCHEMICHICY合成路线制备相互联合的CUO纳米片,然后制备适当的煅烧过程。利用X射线衍射分析和傅里叶变换红外光谱分析来检查新制备的CUO材料的相和内键合性。通过高分辨率扫描电子显微镜分析形态学性质,该显微镜证实了相互连接的CUO纳米片的形成。由于纳米片结构唯一,CUO纳米片以5mVs〜(-1)的扫描速率为667 fg〜(-1)的最大特定电容提供。镀锌电荷/放电测量将638 fg〜(-1)的特定电容以1Ag〜(-1)的电流密度,并提供31.8 W H kg〜(-1)和94 22 W kg〜(-1 )能量和电力密度。循环稳定性研究表现出显着的稳定性,例如81%的初始电容在3000循环伏安循环之后,扫描速率为100mVs〜(-1)。所有这些结果表明,相互联合的CuO纳米片对超级电容器和其他应用领域的可能应用是吉祥的。

著录项

  • 来源
    《Applied Physics》 |2021年第7期|511.1-511.10|共10页
  • 作者单位

    Department of Chemistry T. B. M. L. College Porayar Tamilnadu 609307 India Department of Chemistry Thiru. Vi. Ka. Govt. Arts College Thiruvarur Tamilnadu 610003 India;

    Department of Chemistry Thiru. Vi. Ka. Govt. Arts College Thiruvarur Tamilnadu 610003 India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    CuO; Nanosheets; Sonochemical; Energy storage; Supercapacitors;

    机译:cuo;nanosheets;儿化学;储能;超级电容器;

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