Nickel-Catalyzed Regioselective Carbomagnesation of Methylenecyclopropanes through a Site-Selective Carbon–Carbon Bond Cleavage†

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• 来源
  《Angewandte Chemie International Edition》 |2010年第1期|p.144-147|共4页
• 作者

  Jun Terao Dr.; Masahiro Tomita; Surya#x2005; Prakash Singh Dr.; Nobuaki Kambe Prof.#x2005; Dr.;

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• 作者单位

  Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan), Fax: (+81) 75-383-2514 http://twww.ehcc.kyoto-u.ac.jp/terao/;

  Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan);

  Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan);

  Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan);

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• 关键词

  CC activation; carbomagnesation; cyclopropanes; Grignard reaction; nickel;

  机译：CC活化;羰基化;环丙烷;格氏反应;镍;