Highly Elastic and >200% Reversibly Stretchable Down-Conversion White Light-Emitting Diodes Based on Quantum Dot Gel Emitters

摘要

Combining the characteristics of different materials offers exciting new opportunities for advanced applications in various fields. Herein, white light-emitting diodes (WLEDs) with >200% reversible stretchability are fabricated using six-color quantum dots (QDs) gel emitters. Stable aqueous-phase alloy core/shell QDs with high quantum yield are obtained via ligand exchange using a ternary solvent system. Transparent and highly stretchable gels with large pores are created by binary-solvent-based gelation at low temperatures. Importantly, the QDs and the gel originate from the same two solvents, which make the QDs highly compatible with the gelation process. Consequently, QDs of six different colors are incorporated into the gel without any property degradation. The excellent optical properties of the QDs in the liquid phase (e.g., 17% higher photoluminescence (PL) intensity) are retained in the gel phase. The QD gel (QDG) exhibits elastic deformation up to 200%, with uniform PL over the entire gel. A down-conversion WLED built using the QDG emitter produces cool white light with a color temperature of 6100 K, a color rendering index of 94, and a luminous efficacy of 72 lm W-1. In addition, the performance of the QDG-based WLED remains unchanged even after more than 1000 bending/stretching cycles.