Voltage-Dependent Multicolor Electroluminescent Device Based on Halide Perovskite and Chalcogenide Quantum-Dots Emitters

摘要

Electroluminescent devices based on metal halide perovskites have attracted extensive attention owing to their high external quantum efficiency, excellent color purity, and inexpensive solution process. So far, extensive efforts have been made to improve the efficiency of the monochromatic perovskite light-emitting diodes (LEDs). However, multicolor perovskite-based LEDs are seldom studied. Here, an individual device capable of multicolor emission in response to the passage of external electric bias is demonstrated. With the rational design of the energy band alignment and control of the carrier transport property, color-tunable electroluminescent devices based on inorganic halide perovskite and chalcogenide quantum-dots are fabricated with a wide color tuning range, high color reversibility, and ultrafast color switching. The mechanism of chromaticity tuning is investigated and is explained by the shift of the exciton recombination zone with the driving voltage. The presented work will impact scientific communities by encouraging the manufacture of cost-effective, high-resolution, and full-color displays and human-centric lighting.