Highly Stable Two-Dimensional Tin(Ⅱ) Iodide Hybrid Organic-Inorganic Perovskite Based on Stilbene Derivative

摘要

Hybrid organic-inorganic perovskites have recently emerged as potential disruptive photovoltaic technology. However, the toxicity of lead used in state-of-the-art hybrid perovskites solar cell prevents large-scale commercialization, which calls for lead-free alternatives. Sn-based perovskites have been considered as alternatives but they are limited by rapid oxidation and decomposition in ambient air. Here, an Sn-based two-dimensional hybrid organic-inorganic perovskites [A(2)B(()(n)(-1))Sn(n)I((3)(n)(+1))] (n = 1 and 2) are reported with improved air stability, using bulky stilbene derivatives as the organic cations (2-(4-(3-fluoro)stilbenyl)ethanammonium iodide (FSAI)). The moisture stability of the [(FSA)(2)SnI4] perovskites is attributed to the hydrophobic properties of fluorine-functionalized organic chains (FSA), as well as the strong cohesive bonding in the organic chains provided by H bonds, CH center dot center dot center dot X type H bonds, weak interlayer F center dot center dot center dot F interaction, and weak face-to-face type pi-pi interactions. The photodetector device fabricated on exfoliated single crystal flake of [(FSA)(2)SnI4] exhibits fast and stable photoconductor response.