Enhanced Electrocatalytic Oxygen Evolution Activity by Tuning Both the Oxygen Vacancy and Orbital Occupancy of B-Site Metal Cation in NdNiO_3

摘要

Perovskite oxides have been explored as promising electrocatalysts for the oxygen evolution reaction (OER), while a lack of understanding of key factors impacting the catalytic activity restricts their further design and development. Here, for the first time, the contributions of oxygen vacancy (V-O) and orbital occupancy of B -site cations to the catalytic activity of NdNiO3 films are systematically investigated. It is found that OER activity follows a typical volcano-shaped dependence on the oxygen pressure. In the range of 0.2-10 Pa, proper concentration of V-O can provide a moderate bonding strength with intermediate hydroxyl OH star and the increased ratio of Ni3+/Ni2+ provides a more favorable occupancy of e(g) orbital for the catalytic activity; while in the range of 10-60 Pa, insufficient concentration of V-O leads to an enhanced strength of hybridization between Ni 3d and O 2p band and thus deteriorated catalytic activity. The superior OER catalytic performance can be only achieved with both appropriate concentration of VO and the ratio of B-site metal cations with different valences.