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Adsorption of methyl parathion on PAC from natural waters: the effect of NOM on adsorption capacity and kinetics

机译:天然水中PAC上甲基对硫磷的吸附:NOM对吸附容量和动力学的影响

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摘要

Source water pollution by agricultural chemicals poses great threat to drinking water safety and the removal of such contaminants is a challenge to the water treatment industry. In this work, the adsorption behaviors of methyl parathion (MP) from different natural waters onto different kinds of powdered activated carbons (PAC) were investigated systematically. On the basis of the characterization of the PACs and natural organic matter (NOM), the suitability of PAC with NOM for effective removal of MP was proposed, and the effect of competitive adsorption on MP removal under two PAC dosing patterns was evaluated. The results indicated that NOM adsorption was dependent on the molecular weight (MW) distribution of organic compounds and the pore size distribution of PAC. The mesopore surface area with pore size>3 nm was dominant for the adsorption of the NOM fraction in the range of 500 Da
机译:农用化学品对源水的污染对饮用水安全构成了巨大威胁,而去除此类污染物对水处理行业构成了挑战。在这项工作中,系统地研究了不同自然水中的甲基对硫磷(MP)在不同种类的粉末状活性炭(PAC)上的吸附行为。在表征PAC和天然有机物(NOM)的基础上,提出了PAC与NOM对有效去除MP的适用性,并评估了两种PAC剂量模式下竞争性吸附对MP去除的影响。结果表明,NOM吸附取决于有机化合物的分子量(MW)分布和PAC的孔径分布。在500Da 3nm的中孔表面积是NOM组分吸附的主要部分。较小的MW NOM争夺吸附位对同时吸附模式中的目标有机化合物的吸附有显着影响。在预加载NOM的吸附模式中,相对较大的MW NOM堵塞了孔,导致吸附容量和吸附动力学均明显降低,而MP在PAC上的扩散速度可能受到PAC用量,孔径分布和MW分布的影响。的NOM。

著录项

  • 来源
    《Adsorption》 |2013年第1期|91-99|共9页
  • 作者单位

    State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences">(1);

    State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences">(1);

    State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences">(1);

    State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences">(1);

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Powdered activated carbon (PAC); Natural organic matter (NOM); Suitability; Competitive adsorption; Pore blockage;

    机译:粉末状活性炭(PAC);天然有机物(NOM);适应性;竞争性吸附;毛孔堵塞;
  • 入库时间 2022-08-18 00:09:03

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