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Effect of Compatibility on the Foaming Behavior of Injection Molded Polypropylene and Polycarbonate Blend Parts

机译:相容性对注塑聚丙烯和聚碳酸酯共混零件发泡性能的影响

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摘要

To improve the foaming behavior of a common linear polypropylene (PP) resin, polycarbonate (PC) was blended with PP, and three different grafted polymers were used as the compatibilizers. The solid and foamed samples of the PP/PC 3:1 blend with different compatibilizers were first fabricated by melt extrusion followed by injection molding (IM) with and without a blowing agent. The mechanical properties, thermal features, morphological structure, and relative rheological characterizations of these samples were studied using a tensile test, dynamic mechanical analyzer (DMA), scanning electron microscope (SEM), and torque rheometer. It can be found from the experimental results that the influence of the compatibility between the PP and PC phases on the foaming behavior of PP/PC blends is substantial. The results suggest that PC coupling with an appropriate compatibilizer is a potential method to improve the foamability of PP resin. The comprehensive effect of PC and a suitable compatibilizer on the foamability of PP can be attributed to two possible mechanisms, i.e., the partial compatibility between phases that facilitates cell nucleation and the improved gas-melt viscosity that helps to form a fine foaming structure.
机译:为了改善普通线性聚丙烯(PP)树脂的发泡性能,将聚碳酸酯(PC)与PP共混,并使用三种不同的接枝聚合物作为增容剂。具有不同增容剂的PP / PC 3:1共混物的固体和泡沫样品首先通过熔融挤出,然后在有或没有发泡剂的情况下注塑成型(IM)制成。使用拉伸试验,动态力学分析仪(DMA),扫描电子显微镜(SEM)和扭矩流变仪研究了这些样品的力学性能,热学特性,形态结构和相对流变学特性。从实验结果可以发现,PP和PC相之间的相容性对PP / PC共混物的发泡行为的影响是巨大的。结果表明,将PC与适当的增容剂偶联是提高PP树脂发泡性的潜在方法。 PC和合适的增容剂对PP发泡性的综合影响可归因于两种可能的机理,即促进泡孔成核的各相之间的部分相容性和有助于形成精细发泡结构的改进的熔体粘度。

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