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Tandem Ruthenium-Catalyzed Redox Isomerization–O-Conjugate Addition: An Atom-Economic Synthesis of Cyclic Ethers

机译：串联钌催化氧化还原异构化-O-共轭加成：环醚的原子经济综合

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摘要

An atom-economical method for the convenient synthesis of tetrahydropyrans and tetrahydrofurans is reported. Enones and enals derived from the [IndRu(PPh3)2Cl]-catalyzed redox-isomerization of primary and secondary propargyl alcohols undergo a subsequent intramolecular conjugate addition to provide cyclic ethers in excellent yields.

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期刊名称 other
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Barry M. Trost; Alicia C. Gutierrez; Robert C. Livingston;
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年(卷),期 -1(11),12
年度 -1
页码 2539–2542
总页数 18
原文格式 PDF
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1. Tandem Ruthenium-Catalyzed Redox Isomerization-O-Conjugate Addition: An Atom-Economic Synthesis of Cyclic Ethers [J] . Trost BM, Gutierrez AC, Livingston RC Organic letters . 2009,第12期

机译：串联钌催化的氧化还原异构化-O-共轭加成：环醚的原子经济合成
2. Tandem Ruthenium-Catalyzed Redox Isomerization-O-Conjugate Addition: An Atom-Economic Synthesis of Cyclic Ethers [J] . Trost BM, Gutierrez AC, Livingston RC Organic letters . 2009,第12期

机译：串联钌催化的氧化还原异构化-O-共轭加成：环醚的原子经济合成
3. An Atom-Economic and Selective Ruthenium-Catalyzed Redox Isomerization of Propargylic Alcohols. An Efficient Strategy for the Synthesis of Leukotrienes [J] . Barry M. Trost, Robert C. Livingston Journal of the American Chemical Society . 2008,第36期

机译：丙炔醇的原子经济和选择性钌催化氧化还原异构化。白三烯合成的有效策略
4. Control of Tandem Isomerizations of o-Lithiated Aryl Benzyl Ethers in Flow [C] . Heejin Kim, Hyune-Jea Lee, Dong-Pyo Kim 日本化学会春季年会講演予稿集 . 2018

机译：对流动异锂芳基苄基醚的串联异构化控制
5. Tandem isomerization and cationic polymerization of allyl ethers and novel hybrid monomers bearing cycloaliphatic epoxy and 1-propenyl ether functionalities. [D] . Rajaraman, Suresh Kalpattu. 1998

机译：烯丙基醚和带有环脂族环氧和1-丙烯基醚官能团的新型杂化单体的串联异构化和阳离子聚合。
6. An Atom-Economic and Selective Ruthenium-Catalyzed Redox Isomerization of Propargylic Alcohols. An Efficient Strategy for the Synthesis of Leukotrienes [O] . Barry M. Trost, Robert C. Livingston -1

机译：丙炔醇的原子经济和选择性钌催化氧化还原异构化。白三烯合成的有效策略
7. Bioinspired total synthesis of tetrahydrofuran lignans by tandem nucleophilic addition/redox isomerization/oxidative coupling and cycloetherification reactions as key steps [O] . Pratap R. Jagtap, Ivana Císařová, Ullrich Jahn 2018

机译：通过串联亲核加成/氧化还原异构化/氧化偶联和环醚化反应作为关键步骤，Bioinspired的整体合成
8. Direct Polynitroaliphatic Alcohol Addition to Alkenes. 2. One-Step Synthesis ofbeta-Substituted Polynitroalkyl Vinyl Ethers via an Alternative Transetherification Pathway [R] . Shackelford, S. A., McGuire, R. R., Cochoy, R. E. 1992

机译：直接多元脂族醇加成烯烃。 2.通过替代的Transetherification途径一步合成β取代的聚硝基烷基乙烯基醚

Tandem Ruthenium-Catalyzed Redox Isomerization–O-Conjugate Addition: An Atom-Economic Synthesis of Cyclic Ethers

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