Ni0.5Cu0.5Co2O4 Nanocomposites Morphology Controlled Synthesis and Catalytic Performance in the Hydrolysis of Ammonia Borane for Hydrogen Production

摘要

The catalytic hydrolysis of ammonia borane (AB) is a promising route to produce hydrogen for mobile hydrogen‒oxygen fuel cells. In this study, we have successfully synthesized a variety of Ni0.5Cu0.5Co2O4 nanocomposites with different morphology, including nanoplatelets, nanoparticles, and urchin-like microspheres. The catalytic performance of those Ni0.5Cu0.5Co2O4 composites in AB hydrolysis is investigated. The Ni0.5Cu0.5Co2O4 nanoplatelets show the best catalytic performance despite having the smallest specific surface area, with a turnover frequency (TOF) of 80.2 molhydrogen·min⁻¹·mol⁻¹cat. The results reveal that, in contrast to the Ni0.5Cu0.5Co₂O₄ nanoparticles and microspheres, the Ni_0.5Cu_0.5Co₂O₄ nanoplatelets are more readily reduced, leading to the fast formation of active species for AB hydrolysis. These findings provide some insight into the design of high-performance oxide-based catalysts for AB hydrolysis. Considering their low cost and high catalytic activity, Ni_0.5Cu_0.5Co₂O₄ nanoplatelets are a strong candidate catalyst for the production of hydrogen through AB hydrolysis in practical applications.