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A review on radiation-induced nucleation and growth of colloidal metallic nanoparticles

机译:辐射诱导的胶态金属纳米颗粒的形核与生长

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摘要

This review presents an introduction to the synthesis of metallic nanoparticles by radiation-induced method, especially gamma irradiation. This method offers some benefits over the conventional methods because it provides fully reduced and highly pure nanoparticles free from by-products or chemical reducing agents, and is capable of controlling the particle size and structure. The nucleation and growth mechanism of metallic nanoparticles are also discussed. The competition between nucleation and growth process in the formation of nanoparticles can determine the size of nanoparticles which is influenced by certain parameters such as the choice of solvents and stabilizer, the precursor to stabilizer ratio, pH during synthesis, and absorbed dose.
机译:这篇综述介绍了通过辐射诱导的方法,特别是γ射线辐射合成金属纳米颗粒的介绍。该方法提供了优于常规方法的一些好处,因为它提供了完全还原的高纯度纳米颗粒,而没有副产物或化学还原剂,并且能够控制粒径和结构。还讨论了金属纳米颗粒的成核和生长机理。纳米颗粒形成过程中成核和生长过程之间的竞争可以决定纳米颗粒的尺寸,纳米颗粒的尺寸受某些参数的影响,例如溶剂和稳定剂的选择,前体与稳定剂的比例,合成过程中的pH值以及吸收剂量。

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