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On the unusual amber coloration of nanoporous sol-gel processed Al-doped silica glass: An experimental study

机译:纳米多孔溶胶凝胶处理的掺铝石英玻璃的异常琥珀色:实验研究

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摘要

Silica is the most abundant component on the earth’s surface. It plays an important role in many natural processes. Silica is also a critical material for a wide range of technical applications such as in optics and electronics. In this work, we discuss our recent experimental observation of the unusual amber coloration of aluminum doped sol-gel glass that has not been reported in the past. We characterized Al-doped sol-gel glasses, prepared at different sintering temperature, using a plethora of techniques to investigate the origin of this unusual coloration and to understand their structural and chemical properties. We used these experimental results to test a number of possible coloring mechanisms. The results suggested this coloring is likely caused by temperature-dependent aluminum-associated defect centers associated with different amorphous-to-crystalline ratios of the annealed sol-gel silica glass structures.
机译:二氧化硅是地球表面上最丰富的成分。它在许多自然过程中起着重要作用。二氧化硅还是光学和电子等众多技术应用的关键材料。在这项工作中,我们讨论了我们最近对铝掺杂溶胶-凝胶玻璃异常琥珀色的实验观察,过去没有报道过。我们使用多种技术对在不同烧结温度下制备的掺铝溶胶-凝胶玻璃进行了表征,以研究这种异常着色的起源并了解其结构和化学性质。我们使用这些实验结果来测试许多可能的着色机制。结果表明,这种着色可能是由与温度相关的铝相关缺陷中心引起的,该缺陷中心与退火后的溶胶-凝胶二氧化硅玻璃结构的不同非晶-结晶比有关。

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