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Li-ion Battery Separators Mechanical Integrity and Failure Mechanisms Leading to Soft and Hard Internal Shorts

机译:锂离子电池隔膜机械完整性和故障机制导致软性和硬性内部短路

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摘要

Separator integrity is an important factor in preventing internal short circuit in lithium-ion batteries. Local penetration tests (nail or conical punch) often produce presumably sporadic results, where in exactly similar cell and test set-ups one cell goes to thermal runaway while the other shows minimal reactions. We conducted an experimental study of the separators under mechanical loading, and discovered two distinct deformation and failure mechanisms, which could explain the difference in short circuit characteristics of otherwise similar tests. Additionally, by investigation of failure modes, we provided a hypothesis about the process of formation of local “soft short circuits” in cells with undetectable failure. Finally, we proposed a criterion for predicting onset of soft short from experimental data.
机译:隔板的完整性是防止锂离子电池内部短路的重要因素。局部渗透测试(钉子或圆锥形冲孔)通常会产生零星的结果,其中在完全相似的电池和测试设置中,一个电池发生热失控,而另一个电池显示出最小的反应。我们对隔板在机械载荷下的实验进行了研究,发现了两种不同的变形和破坏机理,这可以解释在其他方面相似的测试中,短路特性的差异。此外,通过研究故障模式,我们提供了关于在无法检测到故障的电池中局部“软短路”形成过程的假设。最后,我们提出了一个根据实验数据预测软短路发作的标准。

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