Guided Slow Continuous Suspension Film Flow for Mass Production of Submicrometer Spherical Particles by Pulsed Laser Melting in Liquid

摘要

Pulsed laser melting in liquid (PLML) is a technique to fabricate submicrometer crystalline spherical particles of various materials by laser irradiation of suspended raw particles with random shapes. To fully exploit the unique features of PLML-fabricated particles (crystalline and spherical) in practice, a mass-production PLML technique is required. To this end, the present study develops a new slit nozzle that guides the suspension film flow into a non-droplet continuous stream with a low flow rate. These two incompatible flow properties (continuity and slowness) are difficult to be realized for a liquid jet to free space. The suspension film flow was irradiated with a typical laboratory scale-flash lamp pumping laser at 30 Hz pulse frequency. Only a single flow passage of the slit nozzle with a few laser pulse irradiation transformed 95% of the raw particles into spherical particles. This spheroidizing ratio exceeded those of low-rate drip flow and high-rate cylindrical laminar flow directly jetted into free space through a Pasteur pipette nozzle. Extrapolating the data obtained from a 20-ml suspension, the average production rate was determined as 195 mg h⁻¹. The high spheroidizing ratio and yield through the slit nozzle is attributable to the uniquely slow but continuous liquid film flow. The structure of the slit nozzle also prevents particles from adhering to the slit wall during continuous laser irradiation. Thus, the suspension film flow through the newly developed slit nozzle can potentially scale up the PLML technique to mass production.