1-Dimethyl­silyl-2-phenyl-3-(η5-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC 1(η5-penta­methyl­cyclo­penta­dien­yl)titanium(III)

摘要

The title compound, [Ti(C10H15)(C20H26Si)], was obtained from the reaction of [Ti{η⁵:η¹-C5Me4(CH2)}(η⁵-C5Me5)] with the alkynylsilane PhC2SiMe2H. The complex crystallizes with two independent mol­ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter­molecular inter­actions or inter­actions involving the Si—H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.