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Microscopic origin of the chiroptical response of optical media

机译:光学介质按摩反应的微观起源

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摘要

The potential for enhancing the optical activity of natural chiral media using engineered nanophotonic components has been central in the quest toward developing next-generation circular-dichroism spectroscopic techniques. Through confinement and manipulation of optical fields at the nanoscale, ultrathin optical elements have enabled a path toward achieving order-of-magnitude enhancements in the chiroptical response. Here, we develop a model framework to describe the underlying physics governing the origin of the chiroptical response in optical media. The model identifies optical activity to originate from electromagnetic coupling to the hybridized eigenstates of a coupled electron-oscillator system, whereas differential absorption of opposite handedness light, though resulting in a far-field chiroptical response, is shown to have incorrectly been identified as optical activity. We validate the model predictions using experimental measurements and show them to also be consistent with observations in the literature. The work provides a generalized framework for the design and study of chiroptical systems.
机译:使用工程化的纳米光子组件增强天然手性介质的光学活性的潜力一直是开发下一代圆二向色光谱技术的中心。通过限制和操纵纳米级的光场,超薄光学元件已实现了在脊骨按摩反应中实现数量级增强的途径。在这里,我们开发了一个模型框架来描述控制光学介质中脊波响应的起源的基本物理学。该模型识别出光学活动是由于电磁耦合到耦合的电子振荡器系统的混合本征态而引起的,而相反惯用右手性光的差分吸收尽管会导致远场手性响应,但已被错误地识别为光学活动。 。我们使用实验测量来验证模型预测,并显示它们也与文献中的观察结果一致。这项工作为整脊系统的设计和研究提供了一个通用的框架。

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