3711-Tris{4-(1R3S4S)-neomenth­yl­oxyphen­yl}tri124triazolo43-a:4′3′-c:4′′3′′-e135triazine–chloro­form–ethanol (1/1/1)

摘要

The title compound, C54H69N9O3·CHCl3·C2H5OH, was prepared by a threefold nucleophilic substitution of p-neomenthyloxyphenyl­tetra­zole on cyanuric chloride followed by threefold cyclo­elimination of nitro­gen and ring closure. The central tris­triazolotriazine is roughly planar with a maximum deviation of 0.089 (7) Å but the adjacent benzene rings are twisted out of this plane. N—C—C—C torsion angles of −80.2 (9), 159.3 (7) and 50.6 (10)° destroy the formal C3 symmetry. Cavities are found between the phen­oxy residues: one is occupied by a chloro­form mol­ecule, another by ethanol forming a hydrogen bond to a triazole ring while two isopropyl groups point into the third void. One methyl group and the chloro­frm mol­ecule are disorderd and were refined using a split model.