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Homopolymerization of Ethylene 1-Hexene Styrene and Copolymerization of Styrene With 13-Cyclohexadiene Using (η5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl2/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl Biphen-3-yl)

机译：（η5-四甲基环戊二烯基）二甲基甲硅烷基（N-Ar）酰氨基-TiCl2 / MAO（Ar= 6-（2-（二乙基硼基）苯基）的乙烯1-己烯苯乙烯的均聚和苯乙烯与13-环己二烯的共聚吡啶-2-基联苯-3-基）

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摘要

The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl)dimethylsilylamido Ti^IV-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (>Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclo-hexadiene is described. The reactivity of >Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (>Ti-3).

机译：带有辅助二乙基硼基保护的吡啶基部分（> Ti-8 ）的半三明治（η5-四甲基环戊二烯基）二甲基甲硅烷基钛基Ti ^{IV 基催化剂的倾向性，该催化剂被甲基铝氧烷（描述了使α-烯烃如乙烯，1-己烯和苯乙烯均聚以及使苯乙烯与1，3-环己二烯共聚的MAO）。与不含6-（2-（2-（二乙基硼基）苯基）吡啶-2-基的类似物（> Ti-3 ）相比，研究了> Ti-8 的反应性。}

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期刊名称 Molecules
作者
Sebnem Camadanli; Ulrich Decker; Christa Kühnel; Ingrid Reinhardt; Michael R. Buchmeiser;
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作者单位

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年(卷),期 2011(16),1
年度 2011
页码 567–582
总页数 16
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
constrained geometry catalyst olefin homopolymerization copolymerization;

机译：几何约束催化剂;烯烃;均聚;共聚;

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专利

1. Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η~5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar')amido-TiCl2/MAO (Ar'=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl) [J] . Sebnem Camadanli, Ulrich Decker, Christa Kühnel Molecules . 2011,第1期

机译：乙烯，1-己烯，苯乙烯的均聚和苯乙烯与1,3-环己二烯的共聚反应，使用（η〜5-四甲基环戊二烯基）二甲基甲硅烷基（N-Ar'）酰胺基TiCl2 / MAO（Ar'= 6-（2-（二乙基硼基）苯基）吡啶-2-基，联苯-3-基）
2. Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (h5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl2/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl) [J] . Sebnem Camadanli, Ulrich Decker, Christa Kühnel, Molecules . 2011,第1期

机译：乙烯，1-己烯，苯乙烯的均聚以及使用（h5-四甲基环戊二烯基）二甲基甲硅烷基（N-Ar'）酰氨基-TiCl2 / MAO（Ar'= 6-（2-（二乙基硼基）苯基）的苯乙烯与1,3-环己二烯的共聚吡啶-2-基，联苯-3-基）
3. Group 4 dimethylsilylenebisamido complexes bearing the 6-[2-(diethylboryl) phenyl]pyrid-2-yl motif: Synthesis and use in tandem ring-opening metathesis/vinyl-insertion copolymerization of cyclic olefins with ethylene [J] . Zou Y., Wang D., Wurst K., Chemistry: A European journal . 2011,第49期

机译：带有6- [2-（二乙基硼基）苯基]吡啶-2-基基序的第4组二甲基甲硅烷基双酰胺基配合物：环烯烃与乙烯的串联开环复分解/乙烯基插入共聚反应的合成及使用
4. Bimetallic effects in the homopolymerization of styrene and copolymerization of ethylene and styrenic comonomers. Scope, kinetics, and mechanism/catalytic in situ synthesis of high energy storage density metal oxide-polyolefin nanocomposites using supported metallocenes. Systematics of nanoparticle, shape, and interfacial characteristics on leakage current density, permittivity, and breakdown strength [D] . Guo, Neng 2007

机译：苯乙烯均聚以及乙烯与苯乙烯共聚单体共聚中的双金属作用。使用负载型茂金属的高能量存储密度金属氧化物-聚烯烃纳米复合材料的范围，动力学和机理/催化原位合成。纳米粒子，形状和界面特性对漏电流密度，介电常数和击穿强度的影响
5. Synthesis and styrene copolymerization of novel trisubstituted ethylenes: 3. Alkoxy ring-substituted isopropyl 2-cyano-3-phenyl-2-propenoates [O] . Gregory B. Kharas, Nita Shinde, Jasmine K. Jody, 2018

机译：新型三取代乙烯的合成和苯乙烯共聚：3.烷氧基环取代的异丙基2-氰基-3-苯基-2-丙酸酯
6. Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (h5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl2/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl) [O] . Michael R. Buchmeiser, Ingrid Reinhardt, Ulrich Decker, 2011

机译：乙烯，1-己烯，苯乙烯的均聚以及使用（h5-四甲基环戊二烯基）二甲基甲硅烷基（N-Ar'）酰氨基-TiCl2 / MAO（Ar'= 6-（2-（二乙基硼基）苯基）的苯乙烯与1,3-环己二烯的共聚吡啶-2-基，联苯-3-基）
7. Review on Styrene Homopolymerization and Copolymerization with Ethylene UsingGroup 4A Catalyst Compounds [R] . Aaltonen, P., Seppaelae, J. V. 1992

机译：用4a族催化剂化合物研究苯乙烯均聚和与乙烯的共聚合

Homopolymerization of Ethylene 1-Hexene Styrene and Copolymerization of Styrene With 13-Cyclohexadiene Using (η5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl2/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl Biphen-3-yl)

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