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Enantioselective Evans-Tishchenko Reduction of β-Hydroxyketone Catalyzed by Lithium Binaphtholate

机译：双萘酚锂催化对映选择性Evans-Tishchenko还原β-羟基酮

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摘要

Lithium diphenylbinaphtholate catalyzed the enantioselective Evans-Tishchenko reduction of achiral β-hydroxyketones to afford monoacyl-protected 1,3-diols with high stereoselectivities. In the reaction of racemic β-hydroxyketones, kinetic optical resolution occurred in a highly stereoselective manner.

机译：二苯基联萘甲酸锂催化非手性β-羟基酮的对映选择性Evans-Tishchenko还原，得到具有高立体选择性的单酰基保护的1,3-二醇。在外消旋β-羟基酮的反应中，动力学光学拆分以高度立体选择性的方式发生。

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期刊名称 Molecules
作者
Tomonori Ichibakase; Masato Nakatsu; Makoto Nakajima;
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作者单位

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年(卷),期 2011(16),6
年度 2011
页码 5008–5019
总页数 12
原文格式 PDF
正文语种
中图分类分子生物学 ;
关键词
Evans-Tishchenko reduction lithium binaphtholate β-hydroxyketone 13-diol enantioselectivity;

机译：Evans-Tishchenko还原;双邻苯二甲酸锂;β-羟基酮;1;3-二醇;对映选择性;

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专利

1. Enantioselective Evans-Tishchenko Reduction of β-Hydroxyketone Catalyzed by Lithium Binaphtholate [J] . Tomonori Ichibakase, Masato Nakatsu, Makoto Nakajima Molecules . 2011 ,第6期

机译：双萘酚锂催化对映选择性Evans-Tishchenko还原β-羟基酮
2. Enantioselective Evans-Tishchenko Reduction of b-Hydroxyketone Catalyzed by Lithium Binaphtholate [J] . Makoto Nakajima, Masato Nakatsu, Tomonori Ichibakase Molecules . 2011 ,第6期

机译：双萘酚酸锂催化对映体的Evans-Tishchenko还原b-羟基酮
3. Lithium acetylides as alkynylating reagents for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate [J] . Kana Tanaka, Kenji Kukita, Tomonori Ichibakase, Chemical Communications . 2011 ,第19期

机译：乙炔锂作为炔基化试剂，用于对萘二甲酸锂催化的酮的对映选择性炔基化
4. Enantioselective Cyanation of Ketones and α,β-Unsaturated Carbonyl Compounds Catalyzed by Chiral Lithium Phosphoryl Phenoxide [C] . Katsuya Yamakawa, Manabu Hatano, Kazuaki Ishihara 日本化学会春季年会講演予稿集 . 2018

机译：由手性锂磷酰苯氧铵催化的酮和α，β-不饱和羰基化合物的对映选择性的氰化物
5. Enantioselective Brønsted acid-catalyzed reaction methodology. Part A: Enantioselective Mannich reaction. Part B: Enantioselective desymmetrization of meso-aziridines [D] . Rowland, Emily Bretherick 2008

机译：对映选择性布朗斯台德酸催化的反应方法。 A部分：对映选择性曼尼希反应。 B部分：内消旋氮丙啶的对映选择性去对称化
6. Copper-catalyzed enantioselective conjugate reduction of αβ-unsaturated esters with chiral phenol–carbene ligands [O] . Shohei Mimura, Sho Mizushima, Yohei Shimizu, 2020

机译：用手性苯酚 - 甲丁配体的铜催化的映选择性缀合物还原αβ-不饱和酯
7. Enantioselective Evans-Tishchenko Reduction of b-Hydroxyketone Catalyzed by Lithium Binaphtholate [O] . Makoto Nakajima, Tomonori Ichibakase, Masato Nakatsu 2011

机译：双萘酚丁酸锂催化的b-羟基酮的对映选择性Evans-Tishchenko还原
8. Lithium-B-Iso-2-ethylapopinocampheyl-9-borabicyclo(3.3.1)nonyl Hydride as anImproved Reagent for Asymmetric Reduction of Unhindered Aliphatic Ketones. Further Evidence for the Improved Enantioselectivity in Reductions by Reagents Containing Increased Ster [R] . Ramachandran, P. V., Brown, H. C., Swaminathan, S., 1990

机译：锂-B-Iso-2-乙基哌啶基-9-硼双环（3.3.1）壬基氢化物作为改进的试剂，用于不受阻碍的脂族酮的不对称还原。含有增加的ster的试剂减少对映选择性的进一步证据

Enantioselective Evans-Tishchenko Reduction of β-Hydroxyketone Catalyzed by Lithium Binaphtholate

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