Adsorptive desulfurization of diesel with mesoporous aluminosilicates

摘要

Mesoporous aluminosilicates (MAS) bearing microporous zeolite units and mesoporous structures were synthesized by the hydrothermal method. Adsorptive desulfurization ability of model oil and hy-drotreated diesel was studied. The effects of template concentration, crystalization time and calcination time were investigated. The desulfurization ability of adsorbents was improved by transitional metal ion-exchanging. The adsorptive desulfurization of diesel was carried out on a fixed-bed system. The results show that the adsorptive capacity is MASMCM-41NaY. The improvement of desulfurization ability of MAS by Cu+ is more significant than that of Ag+.