首页> 中文期刊> 《高分子科学:英文版》 >ENTROPIC CONTRIBUTION TO THE INTERACTION PARAMETER x IN THE POLYMER/OLIGOMER SYSTEM:A LATTICE CLUSTER THEORY CONSIDERATION

ENTROPIC CONTRIBUTION TO THE INTERACTION PARAMETER x IN THE POLYMER/OLIGOMER SYSTEM:A LATTICE CLUSTER THEORY CONSIDERATION

             

摘要

Entropic contribution to the interaction parameter xeff in the model incompressible polymer/oligomer system is calculated by the lattice cluster theory (LCT). It is found that in the oligomer solvent, there exists a wide concentration range that the non-combinatorial "entropic interaction" term xeff φ1φ2 perceptibly counteracts the mean field combinary entropy △SMF. With the increase of the solvent size, both xeff and the ratio xeff φ1φ2/ASMF first reach their maximum and finally become trivially to zero. It is worth noting that no any demixing was found in the current calculation. This makes the controversial idea "entropically driven demixing" even elusive. However, we propose that further work on

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