Microkinetics of H2S Removal by Zinc Oxide in the Presence of Moist Gas Atmosphere

摘要

The microkinetics of H2S removal by ZnO desulfurization in H2O-CO2-N2, H2O-CO-N2 andH2O-O2-N2 gas mixtures was studied by thermogravimetric analysis. Experiments were carried out with100 120 mesh ZnO powder at temperatures from 473 K to 563 K. The results show that the kineticbehaviors of desulfurization could all be described by an improved shrinking-core model. The activationenergies of the reaction and the diffusion in different gas atmospheres were estimated.