首页> 中文期刊> 《能源化学:英文版》 >Catalytic combustion of soot particulates over La_(2-x)K_xNiMnO_6 catalysts

Catalytic combustion of soot particulates over La_(2-x)K_xNiMnO_6 catalysts

         

摘要

Nanosized La2-xKxNiMnO6 catalysts with ABO3 type perovskite-like structure were prepared by auto-combustion method using citric acid as a ligand to control particle size and morphology.The structures and properties of these perovskite-like oxides were investigated by X-ray powder diffraction(XRD)and temperature-programmed reduction(TPR).The catalytic activities for soot combustion were evaluated by temperature- programmed oxidation(TPO)with pure O2 and O2/NOx as oxidant,respectively.In the La2-xKxNiMnO6 catalysts,the partial substitution of K at A-site leads to an increase of the concentrations of high valence cation and oxygen vacancy,which enhance the catalytic activity for soot combustion.The optimal substitution amount of K was equal to x=0.4 among these samples.Tp(peak temperature)in O2-TPO profile was 420-C and Tp in O2/NOx-TPO profile was 370-C over La1.6K0.4NiMnO6 catalyst for soot particulates combustion under loose contact conditions between catalyst and soot.

著录项

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号