首页> 中文期刊> 《能源化学:英文版》 >Influence of Sulfation on the Catalytic Activity of Ni-ZrO_2 for NO Reduction with Propane in Excess Oxygen

Influence of Sulfation on the Catalytic Activity of Ni-ZrO_2 for NO Reduction with Propane in Excess Oxygen

         

摘要

Selective catalytic reduction (SCR) of nitric oxide with propane in excess oxygen was investi- gated on Ni-ZrO2 (NZ) and sulfated Ni-ZrO2 (SNZ), prepared by coprecipitation from a mixture of nickel nitrate-zirconium oxychloride followed by modifying with (NH4)2SO4. It was found that sulfated Ni-ZrO2 catalyst showed higher activity for the SCR of NO with propane than that of Ni-ZrO2. The structural and surface properties of catalysts were studied by XRD, BET, SEM and FT-IR of pyridine adsorption. The experimental results indicated that the modification of (NH4)2SO4 resulted in the generation of strong Br?nsted and Lewis acid sites and promoted the dispersion of the Ni species, which could lead to higher NO conversion and propane efficiency in NO reduction.

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