超级13Cr马氏体不锈钢抗SSC性能研究

摘要

H2S stress corrosion cracking (SSC) behavior of super 13Cr martensitic stainless steel at the simulated and standard environments has been studied with four-point bent test, electrochemical measurement as well as Scanning Electron Microscopy (SEM) analysis methods. The results show that the super 13Cr martensitic stainless steel behaves a high SSC susceptibility at the standard environments, and the cracks stem from surface corrosion pits because of the occurrence of H2S and Clmaking the pitting potential of super 13Cr martensitic stainless steel decreased significantly. While at the simulated environments, the SSC susceptibility of super 13Cr martensitic stainless steel decreased, and no cracks are found on the surface of the test specimen.%采用四点弯曲实验方法、电化学测试技术及扫描电子显微镜(SEM)等分析手段研究了超级13Cr马氏体不锈钢在模拟工况和标准工况中的H2S应力腐蚀开裂(SSC)行为.结果表明:超级13Cr 马氏体不锈钢在标准工况条件下具有很高的SSC敏感性,裂纹起源于表面点蚀坑处,H2S腐蚀性气体的存在及Cl-浓度的增加显著降低超级13Cr马氏体不锈钢的点蚀电位,明显增加超级13Cr马氏体不锈钢的SSC敏感性;在模拟工况条件下,超级13Cr发生SSC的敏感性降低,没有发生开裂现象.