The series of Sr2-x□□ FeMoO6 (0 ≤x ≤ 0.04) were prepared by standard solid-state reaction.The crystal structures for the ordered double perovskite oxides are investigated.The GSAS refinements of X-ray powder diffraction show that all the samples are single phase and have the I4/m symmetry.Crystal parameters of the series have obvious change with vacancy doping.The anti-site defect in Sr2FeMoO6 was 91.02% and decrease to 61.26% for Sr1.96□0.4FeMoO6.The Bragg diffraction peak information was obtained from the GSAS refinements of X-ray powder diffraction.%采用传统高温固相反应法制备了空位掺杂的系列样品Sr2-x□xFeMoO6 (0≤x≤0.04),详细研究了其晶体结构.X射线粉末衍射结果表明该系列样品均为四方晶系,空间群为I4/m.晶胞参数随掺杂量有明显的变化趋势.空位的含量调控反位缺陷的浓度,Fe/Mo有序度从未掺杂时的91.02%降低到x=0.04时的61.26%.由Rietveld精修得到该系列样品详细的布拉格衍射峰的峰位信息.
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