In this study, we report the cost-effective and simple synthesis of carbon-coated α-MnO2nanoparticles(α-MnO2@C) for use as cathodes of aqueous zinc-ion batteries(ZIBs) for the first time. α-MnO2@C was prepared via a gel formation, using maleic acid(C4H4O4) as the carbon source, followed by annealing at low temperature of 270 °C. A uniform carbon network among the α-MnO2 nanoparticles was observed by transmission electron microscopy. When tested in a zinc cell, the α-MnO2@C exhibited a high initial discharge capacity of 272 m Ah/g under 66 m A/g current density compared to 213 m Ah/g, at the same current density, displayed by the pristine sample. Further, α-MnO2@C demonstrated superior cycleability compared to the pristine samples. This study may pave the way for the utilizing carbon-coated MnO2 electrodes for aqueous ZIB applications and thereby contribute to realizing high performance eco-friendly batteries.
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机译:在这项研究中,我们首次报道了成本低廉且简单的碳包覆α-MnO2纳米颗粒(α-MnO2@ C)的合成方法,该颗粒用作水性锌离子电池(ZIBs)的阴极。以马来酸(C4H4O4)为碳源,通过凝胶形成法制备α-MnO2@ C,然后在270℃的低温下退火。通过透射电子显微镜观察到α-MnO2纳米颗粒之间均匀的碳网络。当在锌电池中测试时,α-MnO2@ C在66 m A / g电流密度下显示出272 m Ah / g的高初始放电容量,而在相同电流密度下显示为213 m Ah / g。原始样品。此外,与原始样品相比,α-MnO2@ C具有优异的循环能力。这项研究可能为在水性ZIB应用中使用碳包覆的MnO2电极铺平道路,从而有助于实现高性能的环保型电池。
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