5-甲基-4-噁异唑-3-甲基-2-噻吩甲酰腙及其 Co（Ⅱ）配合物的合成与表征

摘要

以5-甲基-4-噁异唑甲酰肼为原料，与3-甲基-2-噻吩甲醛反应合成5-甲基-4-噁异唑-3-甲基-2-噻吩甲酰腙，再将其作为配体与钴离子合成相应的钴配合物，对其进行红外、核磁共振氢谱、紫外-可见等表征确认结构，并对配体及其配合物的荧光性能进行测定。荧光测定表明，配体及其配合物都较强的荧光性能，因此可作为潜在的光活性材料。%3-Methyl-2-thiophene aldehyde-5-methyl-4-isoxazole formyl hydrazone was synthesized with 5-methyl-4-isoxazole formyl hydrazine as raw material. Then its Co(Ⅱ) metal complex was prepared in alcohol solvent. The structures of the ligand and the Co(Ⅱ) complex were characterized by IR,1H-NMR,UV-Vis and MS, etc. Luminenscence measurement result shows that both the ligand and the complex can emit fluorescence.