含有三苯胺环类席夫碱的合成

摘要

以4,4'-二甲酰基三苯胺为原料,通过Wittig和胺醛缩合反应合成了两个含有三苯胺环席夫碱类化合物——4-(对甲基苯乙烯基)-4'-亚(α-萘胺)甲基三苯胺和4-(对甲基苯乙烯基)-4'-亚(2-氨基芴)甲基三苯胺,其结构经1H NMR,13CNMR和IR确证.%Two schiff bases compounds containing triphenylamine ring,4-(p-methylstyryl)-4'-(α-naphthylamine) methylenetriphenylamine and 4-(p-methylstyryl)-4'-(2-aminofluorene) methylenetri-phenylamine,were synthesized by Wittig reaction and aldimine condensation reaction from 4,4'-di-formyltriphenylamine.The structures were confirmed by 1 H NMR,13C NMR and IR.