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Corrosion protection of composite coating combining ceramic layer, copper layer and benzotriazole layer on magnesium alloy

机译:镁合金上陶瓷层,铜层和苯并三唑层的复合涂层的腐蚀防护

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摘要

A novel composite coating was fabricated on AZ91 magnesium alloy by applying a composite surface treatment which combined the methods of plasma electrolytic oxidation(PEO)pre-treatment,electroless copper and benzotriazole(BTA)passivation. The cross-section microstructures and chemical compositions of coating were examined using scanning electron microscopy(SEM) equipped with energy dispersive analysis of X-rays(EDX).Potentiodynamic polarization curves and salt spray tests were employed to evaluate corrosion protection of the coating to substrate in 5%NaCl solution.It is indicated that electroless copper produces a rough interface between the electroless copper layer and the ceramic layer.The corrosion potential shifts to the positive direction significantly and the current density decreases by more than one order of magnitude.There is no visible galvanic corrosion pits on the surface of the composite coating combination of PEO and electroless copper after 168 h neutral salt spray testing.The color of copper after BTA immersion could be held more than 60 d.
机译:结合等离子电解氧化(PEO)预处理,化学镀铜和苯并三唑(BTA)钝化的方法,对复合材料进行了AZ91镁合金表面涂层的制备。使用配有X射线能量色散分析仪(EDX)的扫描电子显微镜(SEM)检查涂层的横截面微观结构和化学成分,并用电势极化曲线和盐雾试验评估涂层对基材的防腐性能在5%NaCl溶液中,表明化学镀铜在化学镀铜层和陶瓷层之间产生了粗糙的界面,腐蚀电位明显向正方向移动,电流密度下降了一个数量级以上。经过168小时的中性盐雾试验后,PEO和化学铜的复合涂层的表面上没有可见的电化腐蚀坑。BTA浸没后的铜色可以保持60 d以上。

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