一个生物相关单一手性二维金属有机鲱骨形分子网格: 双-3-氨基-(S)-酪氨酸钴(Ⅱ)

摘要

The first example of homochiral two-dimensional neutral cobalt (Ⅱ)-3-amino-( S)-tyrosine (ATYR) coordination polymer,bis(3-amino-(S)-tyrosinato)cobalt(Ⅱ)1 was synthesized under the hydrothermal reaction of Co(ClO4)2·6H2O with ATYR in which 1 displays modest second harmonic generation response.