Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant

摘要

Ammonium bisulfate(ABS)is a viscous compound produced by the escape NH_(3) in the NO reduction process and SO_(3) in the flue gas at a certain temperature,which can cause the ash corrosion of the air preheater in coal-fired power plants.Therefore,it is essential to study the formation temperature of ABS to prevent the deposition of ABS in air preheaters.In this paper,the SO_(3) reaction kinetic model is used to analyze the SO_(3) generation process from coal combustion to the selective catalytic reduction(SCR)exit stage,and the kinetic model of NO reduction is used to analyze the NH_(3) escape process.A prediction model for calculating the ABS formation temperature based on the S content in coal and NO reduction parameters of the SCR is proposed,solving the difficulty of measuring SO_(3) concentration and NH_(3) concentration in the previous calculation equation of ABS formation temperature.And the reliability of the model is verified by the actual data of the power plant.Then the influence of S content in coal,NH_(3)/NO_(x) molar ratio,different NO_(x) concentrations at SCR inlet,and NO removal efficiency on the formation temperature of ABS are analyzed.